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Kinetic and Energetic Correlations in the Reaction of
Vitamin-C Tablets

مؤلف البحث
Seddique M. Ahmed and Mohamed M. Shahata
قسم البحث
مجلة البحث
Chemical Science International Journal
(Past name: American Chemical Science Journal)
المشارك في البحث
الناشر
NULL
تصنيف البحث
1
عدد البحث
25 (1)
موقع البحث
DOI: 10.9734/CSJI/2018/45058
سنة البحث
2018
صفحات البحث
1-7
ملخص البحث

The oxidation time based on the fitting of experimental data was taken out. Drawing of the
Absorbance (λmax=265 nm) vs. oxidation time (sec) of Vitacid C by K2 CrO4 were studied. Energy
consumed during oxidative degradation of vitamin-C(Vit-C) Tablets in aqueous potassium chromate
(K2CrO4) medium was studied spectrophometrically at 25°C. The reduction of the absorbance at~
265 nm with increasing time was scanned. A good linearity (R-square ≥ 0.99). The slope (EC/ppm)
vs reductant (Vit-C/ppm) at constant oxidant is about 1.218, while, the slope of EC vs. oxidant
(K2CrO4 /ppm) is about 3.653. Calculations suggest that the EC during reduction of Cr (VI) to Cr (III)
is about three times of magnitude faster than the oxidation of the Vit - C sample.