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Enhanced dual fluorescence quenching of red and blue emission carbon dots by copper dimethyldithiocarbamate for selective ratiometric detection of ziram in foodstuff and water

مؤلف البحث
Khalid Alhazzani, Ahmed Z Alanazi, Aya M Mostafa, James Barker, Hossieny Ibrahim, Mohamed M El-Wekil, Al-Montaser Bellah H Ali
ملخص البحث

The monitoring of ziram levels is of vital importance due to its widespread application in agriculture and the possible risks it poses to human health and the ecosystem. This work proposes an innovative approach for the highly sensitive and selective sensing of ziram, a widely used dithiocarbamate fungicide, through the formation of copper dimethyldithiocarbamate Cu)DDC)2 assisted dual quenching of red and blue emission carbon dots (R/NCDs and B/NSCDs). When ziram is added to a system containing copper-bound B/NSCDs and R/NCDs, the displacement of ziram zinc ions by copper ions leads to the formation of a yellow-colored Cu)DDC)2 complex. This complex induces significant quenching of the fluorescence emissions from both types of carbon dots, consequently enhancing the sensitivity of the detection method. Comprehensive characterization of the R/NCDs and B/NSCDs was conducted using …

تاريخ البحث
قسم البحث
مجلة البحث
Microchemical Journal
المشارك في البحث
الناشر
Elsevier
عدد البحث
204
سنة البحث
2024
صفحات البحث
111092