An inertial electrostatic confinement (IEC) fusion device accelerates ions, such as deuterium (D) or tritium (T), to produce nuclear fusion and generate neutrons. The IEC's straightforward configuration consists of a concentric spherical transparent cathode at a negative bias surrounded by a grounded spherical anode. The effects of cathode properties on the neutron production rate (NPR) remain, to date, inadequately studied. This study aims to determine the impact of the cathode material on the NPR by investigating fusion reactions on the cathode surface. Two buckyball-shaped cathodes made of stainless steel (SS) and titanium (Ti), both of 5 cm diameter, fabricated by selective laser melting and 3D printing, are used for this investigation. A SS spherical chamber of 25 cm inner diameter is used as an anode in this experiment. A performance evaluation of surface fusion reaction in the IEC using SS and Ti grids is