This paper presents a comprehensive numerical investigation to predict the human breathing zones (BZs) in crowded semi-outdoor environments. The computational domain consisted of a nine-human block array with integrated nasal cavities subjected to the lower part of the atmospheric boundary layer. Five crowding levels, seven wind directions, and inflow ambient air temperatures (ranging from 10 to 31 ◦C) were tested to examine the horizontal and vertical formations of the BZs. Validation and verification tests were performed through comparisons with experimental results, a grid independence test, and an evaluation of various randomized distribution scenarios to minimize the uncertainties of the computational fluid dynamics analyses. The horizontal extension of the BZs tripled as the crowding level increased from 0.325 to 4.0 m2 /capita. However, the lateral extension was insensitive and remained within 10 cm of the nostrils. Human models can inhale air close to the cheek, neck, and shoulders when an oblique flow is assumed. As the air temperature increased, individuals tended to inhale air from the upper regions, which was influenced by the interrelated thermal properties of the human body. Consequently, under high-temperature conditions, there may be an increased probability of gasphase contaminant inhalation over greater horizontal distances.